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There are many materials that are being explored for 3D Printing, however you will find that the two dominant plastics are ABS and PLA. Both ABS and PLA are known as thermoplastics; that is they become soft and moldable when heated and return to a solid when cooled. This process can be repeated again and again. Their ability to melt and be processed again is what has made them so prevalent in society and is why most of the plastics you interact with on a daily basis are thermoplastics.
Both ABS and PLA do best if, before use or when stored long term, they are sealed off from the atmosphere to prevent the absorption of moisture from the air. This does not mean your plastic will be ruined by a week of sitting on a bench in the shop, but long term exposure to a humid environment can have detrimental effects, both to the printing process and to the quality of finished parts.
ABS - Moisture laden ABS will tend to bubble and spurt from the tip of the nozzle when printing; reducing the visual quality of the part, part accuracy, strength and introducing the risk of a stripping or clogging in the nozzle. ABS can be easily dried using a source of hot (preferably dry) air such as a food dehydrator.
PLA - PLA responds somewhat differently to moisture, in addition to bubbles or spurting at the nozzle, you may see discoloration and a reduction in 3D printed part properties as PLA can react with water at high temperatures and undergo de-polymerization. While PLA can also be dried using something as simple as a food dehydrator, it is important to note that this can alter the crystallinity ratio in the PLA and will possibly lead to changes in extrusion temperature and other extrusion characteristics. For many 3D Printers, this need not be of much concern.
ABS - While printing ABS, there is often a notable smell of hot plastic. While some complain of the smell, there are many who either do not notice it or do not find it to be particularly unbearable. Ensuring proper ventilation in small rooms, that the ABS used is pure and free of contaminants and heated to the proper temperature in a reliable extruder can go a long way in reducing the smell.
PLA - PLA on the other hand, being derived from sugar gives off a smell similar to a semi-sweet cooking oil. While it certainly won't bring back fond memories of home-cooked meals, it is considered by many an improvement over hot plastic.
Both ABS and PLA are capable of creating dimensionally accurate parts. However, there are a few points worthy of mention regarding the two in this regard.
ABS - For most, the single greatest hurdle for accurate parts in ABS will be a curling upwards of the surface in direct contact with the 3D Printer's print bed. A combination of heating the print surface and ensuring it is smooth, flat and clean goes a long way in eliminating this issue. Additionally, some find various solutions can be useful when applied beforehand to the print surface. For example, a mixture of ABS/Acetone, or a shot of hairspray.
For fine features on parts involving sharp corners, such as gears, there will often be a slight rounding of the corner. A fan to provide a small amount of active cooling around the nozzle can improve corners but one does also run the risk of introducing too much cooling and reducing adhesion between layers, eventually leading to cracks in the finished part.
PLA - Compared to ABS, PLA demonstrates much less part warping. For this reason it is possible to successfully print without a heated bed and use more commonly available "Blue" painters tape as a print surface. Ironically, totally removing the heated bed can still allow the plastic to curl up slightly on large parts, though not always.
PLA undergoes more of a phase-change when heated and becomes much more liquid. If actively cooled, much sharper details can be seen on printed corners without the risk of cracking or warp. The increased flow can also lead to stronger binding between layers, improving the strength of the printed part.
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